A systematic study of radiation damage in transition metal chloride complexes with 1,5-cyclooctadiene ligands using diffraction and spectroscopy
نویسندگان
چکیده
منابع مشابه
synthesis and dna interaction studies of new cobalt (ii) complexes containing different dinitrogen aaromatic ligands with calf thymus dna using different spectroscopy methods
در این مطالعه بر هم کنش این چهار کمپلکس با dna تیموس گوساله توسط روش های اسپکتروفتومتری، فلوریمتری، دو رنگ نمائی دورانی، و ویسکوزیمتری بررسی شدند تا اثر استخلاف های متیل بر روی لیگاندهای فنانترولین بررسی گردد.
Synthesis and characterization of some transition metal complexes with new mixed-donor schiff base ligands derived from 2-hydroxynaphthaldehyde
2-[3-(2-Formylnaphthoxy)-2-hydroxypropoxy] naphthaldehyde (1) have been prepared by reaction of 2-hydroxynaphthaldehyde with 1,3-dichloro-2-propanol. New N2O3 macro-acyclic ligands (L1, L2) synthesized from the reaction of (1) with aniline or cyclohexylamine. Ni (II), Co (II) and Cu (II) complexes was prepared from reaction of Schiff-bases with metal chloride and nitrate salts. All of these com...
متن کاملSynthesis and characterization of some transition metal complexes with new mixed-donor schiff base ligands derived from 2-hydroxynaphthaldehyde
2-[3-(2-Formylnaphthoxy)-2-hydroxypropoxy] naphthaldehyde (1) have been prepared by reaction of 2-hydroxynaphthaldehyde with 1,3-dichloro-2-propanol. New N2O3 macro-acyclic ligands (L1, L2) synthesized from the reaction of (1) with aniline or cyclohexylamine. Ni (II), Co (II) and Cu (II) complexes was prepared from reaction of Schiff-bases with metal chloride and nitrate salts. All of these com...
متن کاملFerrocenylalkynes as ligands in transition metal complexes
Several ferrocenylalkynes have been prepared and their reaction with dicobalt octacarbonyl led to the formation of [Co2(CO)6(μ-η 2 : η-ethynylferrocene)] 1, [Co2(CO)6(μ-η 2 : η-1,4-bis(ferrocenyl)butadiyne)] 2, [(Co2(CO)6)2(μ-η : η,μ-η : η-1,4-bis(ferrocenyl)butadiyne)] 3, [Co2(CO)6(μ-η 2 : η-1-ferrocenylethynyl-2-hydro-1,2-dihydro[60]fullerene)] 4, [Co2(CO)6(μ-η 2 : η-1,1’-bis(phenylethynyl)fe...
متن کاملSupported Homogeneous Catalysts TRANSITION METAL COMPLEXES WITH POLYMERIC LIGANDS
Almost all industrial catalysts are heterogeneous, the reaction taking place on a solid surface. During the past decade homogeneous catalysts, soluble in the liquidphase reactant, have received a great deal of attention, although they have so far found only limited industrial use, chiefly because of the di$culty of their separation from the reaction products. More recently an intermediate type,...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2018
ISSN: 2053-2733
DOI: 10.1107/s2053273318089271